Q - When is a triangle not a triangle?

A - When it's a pyramid
There are two molecular shapes that could be described as triangular (or trigonal). One is a...errr...a triangle and it is referred to as trigonal planar. The other is effectively a triangular based pyramid, called equally obviously, trigonal pyramidal. The reasons behind the differences in the two are important.

Trigonal planar is flat (i.e planar) so imagine a triangle with three atoms at each corner and one in the middle. Each of the corner atoms are 120degrees apart (i.e. 360/3 = 120). You get trigonal planar when you have three bonded pairs and no lone pairs as that is the furthest the electron pairs can get away from each other. an example is BF3

Trigonal pyramidal is like...erm... a pyramid but a pyramid with a trigonal base (hence the name). The bond angles are 107degrees (no way of working that out you just have to remember). You get trigonal pyramidal when you have 3 bonded pairs and 1 lone pair. The lone pair is more repulsive and pushes the bonded pairs down and  away from being trigonal planar (which is what you would get if the lone pair wasn't there). An example is NH3

P.S. The purple lump on the trigonal pyramidal isn't a comedy hat it is a lone pair of electrons.